I have synthesised a ruthenium doped lanthanum oxide catalyst for photo catalysis. Please suggest the best method from cyclic voltametery , chronoamperiometry , impedance spectroscopy.
Those thing depends on which system (which condition, reaction, etc) you are using and what kind of EIS data are getting.Then only you can choose the correct circuit.
Typically an EIS plot contains a semicircle and a straight line. If your EIS data is similar then you can use a simplified Randels circuit consisting of a solution resistance, a charge transfer resistance, warburg resistance and a constant phase element. You can find the capacitance from this circuit.