in my opinion, the low cost and better method for synthesizing WO3 Nanomaterial is by using Cetyl Trimethyl Ammonium Bromide Supermolecular Template a cationic surfactant (cetyl trimethyl ammonium bromide)can be used as the organic supermolecular template and WCl6 and NH4OH used as the inorganic precursor and counter ion source. for details can read the following reference;
Preparation of WO3 Nanoparticles Using Cetyl Trimethyl Ammonium Bromide Supermolecular Template