In fact, WinPLOTR can use a lot of formats, including dat, xy, xrdml, gsas... First you need to know the format of your experimental file. If it cannot be opened by WinPLOTR directly, you can convert it with ConvX or PowDLL into acceptable one.
The format shown by Masoud Shajahani is ok. But ymake sure for extension as ".dat". Also check it once by opening it in the notepad. We have to give the same name in pcr file then it can open this file automatically.