You can consider the use of atomic spectrometry, as well as ICP methods, as the methods of first choice for the quantification of heavy metals in the soil samples.
Nodirabonu Sultonova Here are my suggestions: 1) visual crop observations; 2) the electrical conductance of soil solution extracts or extracts at higher than normal water contents; 3) in situ measurement of electrical resistivity; 4) noninvasive measurement of electrical conductance with EM; and most recently 5) in situ measurement of electrical conductance with TDR.