The multi-barrier concept is adopted and applied for different types of radioactive waste. In principle, the multi-barrier consists of three successive barriers: waste packages, the engineered structure and the geological formation of the site that together provide physical and environmental levels of protection. The first barrier is the conditioned immobilized waste typically through cementation (ILW-LL) or vitrification (HLW-LL). The second one is the corrosion-resistant canisters (e.g., carbon steel for HLW-LL) that contain the immobilised waste. The last barrier is the host rock together with the disposal structure, which ensures isolation, stability and safety of the radioactive waste over a very long period of time. What does vitrification mean during the high-level radioactive waste (HLRW) disposal?