Given the fact that plants growing in green roofs have a very limited space to develop their root system, I think that their potential for carbon sequestration remains minimal. However, when we consider the other ecological services provided by a green roof (e.g.: cooling of the building, avoidance of rain water run off, contribution to improving air quality in the city, extra habitat/nectar source for pollinators), then the cumulative environmental benefits of a green roof become substantial to legitimize its design and construction.
Yes, I agree with your opinion. Moreover, in City area, if Government will make it mandatory --atleast 20 or 30% roof top open space to be made green, it may be helpful to sequester carbon besides other additional benefits.