If is behavior is same and doesn't vary by varying voltage
EIS
Potentiostatic impeance
the potential your option has to be within the range of interest for the phenomenon to take place. You can find the potential from your CV results.
It will depend of the electrochemical process you want to study, could you explain a little bit more your question?
pl donot use the word voltage- say at constant potential - it is possible to do EIS at all imposed potentials - see my papers
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