Thank you Gildas, but there is no chance of presence of organic molecules in the solution, it is just concentrated HF and vanadate in water, but the fluoride does not coordinate to vanadium.
Dear Lukáš, it seems that signal at -86 could be attributed to the nonhydrated (or low hydrated, or coordinated) fluoride ion (cation is [VO2(H20)4]+). But I am not sure completely. Thus, shifts of F- is ranging from -72 (CH3CN) to -86 (THF). The shift at -129 should can be attributed to fully hydrated F- (KF(aq) shows shift about -125). The shift at 169 must be HF. Please, see several references:
Agree with above - also remember Hf can start to etch certain types on NMR tubes for instance I have observed SiF6 2- and Al and Na F type species in these chemical shift ranges which I confirmed using Si Al and Na Nmr experiments
At -129 to -132 ppm, a signal of SiF6 2- (etched from the NMR tude by acid fluoride-containng solutions) is observed. You can identify it due to the presence of satellites 19F--129Si (J = 110 Hz).
As pointed out by Gayane, the -129 ppm signal is due to SiF62- . The -169 ppm signal is very likely from HF/F- (H-bonded species) , and the -86 ppm signal is, as Dmitrii suggested, probably from [VO2(H2O)4]+F-. Note that the [VO2(H2O)4]+ solution is said to be light yellow in color. To minimize/eliminate the SiF62- signal, use PTFE HF acid-safe NMR tubes and caps. Good luck in your research.