It appears that the crystal structure of the pure sample is a BiFeO3 and you doped 20% of samarium in the Bi site so that the atomic position of is the same that of the Bi, please find CIF with R 3 c and R -3 m space group and atomic positions jpg files the following attachment
We doped samarium (Sm) BFO from 0% to 20%. And at 20% there is a structural transition from R3c to Pnma. As shown in the attached files . But my base does not contain a Pnma structure.
Article Evolution of structural transition, grain growth inhibition ...