The second law of thermodynamics must be satisfied in order to hold true
1,Hydrostatic equilibrium pa=pb+ro*g*hab
2,Fluctuation equilibrium (dp/dv)/V @ a=@ b
It is impossible to satisfy both at the same time. The second law of thermodynamics is incorrect. Please refer to the following text and pictures for details.
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1,pa=pb+ro*g*hab,(dp/dv)/v@a>@b=>
2,δpa>δpb=>
3,δE @a >@b =>
4,δE from a to b=>
5,Ta
6,the Second Law of Thermodynamics Law is end.
(δ--Fluctuation )
This situation can occur,
The mixture of CO2 and H2 in a gravitational field has a high concentration of CO2 at the bottom of the container (point a) and a high concentration of "dp/dv"/v, while the concentration of CO2 at the top of the container is low (point b) and a low concentration of "dp/dv"/v. According to the above logic, Ta