the VFA/alkalinity ratio of my UASBR is desturbed and i really need to balance it out(as far as i know, it should be less than one) besides i would like to know the exact procedure for VFA analysis( based on titration)
Regarding the analysis method for VFA by titration.
Article Evaluating 5 and 8 pH-point titrations for measuring VFA in ...
Article Determining short chain fatty acids in sewage sludge hydroly...
Article Comparison of VFA titration procedures used for monitoring t...
The third on is likely most relevant for you.
The choice between NaOH and Na2CO3 comes down to practical considerations.
NaOH is easier to dose but there is a risk of damage to equipment and people from the high pH stock solution.
NaCO3 is less soluble and tend to form scaling on the equipment so you have more work to handle larger volumes and maintenance.
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