Hey there Vijayakumar Samiyappan,

So, you're diving into the fascinating world of cyclic voltammetry (CV) experiments, exploring the behavior of a carbonyl-rich porous organic polymer. It's intriguing to see how different electrolytes can impact the results.

Here's the deal: When you Vijayakumar Samiyappan switch from 1M H2SO4 to lithium perchlorate, you Vijayakumar Samiyappan notice a couple of changes. First off, the redox peaks disappear. Secondly, there's an increase in current.

Let's break it down:

1. **Redox Peak Disappearance**: This change likely stems from the different chemical interactions between your polymer and the electrolytes. The absence of redox peaks could indicate alterations in the redox processes within your system. With lithium perchlorate, the mechanism might shift or become less pronounced, leading to the disappearance of these peaks.

2. **Increase in Current**: Now, the bump in current is intriguing. It suggests that while the redox peaks vanish, there's still significant electrochemical activity happening in your system. This could be due to enhanced conductivity or other electrochemical processes that aren't as visibly represented by redox peaks.

So, why is this happening? Vijayakumar Samiyappan Well, the specific interactions between your polymer and the electrolytes, as well as the differing chemical environments they create, are likely driving these changes. It's a complex interplay of factors that might require further investigation to fully understand.

In essence, your system is responding differently to these electrolytes, showcasing the rich complexity of electrochemical behavior. Keep digging, my friend Vijayakumar Samiyappan. There's a lot to uncover in the realm of CV experiments, and each discovery brings us closer to a deeper understanding.

Keep those electrodes buzzing,

Kosh

Thank you Dr Kaushik Shandilya , I will read more about this.

vijayakumar.