I am experiencing difficulties with the dispersion of carbon nanotubes in water. Can anyone offer recommendations on methods to achieve maximum dispersion?
i disperse them in 1% SDS, then attached a heterobifunctional linker that contains a phospholipid at one end and a maleimide group to react w/ cysteine residues on proteins or peptides. you can just block the maleimide w/ L-cysteine if you do not want it to react. dialyze away the SDS using deionized water
You can try a common surfactant like gum arabic. Usually gum arabic and carbon nanotubes solutions need to be sonicated for a while (~ 1 hr) to obtain the desired dispersion.
Without chemical modification it will very difficult or impossible to obtain a good aqueous dispersion at such a high concentration. Even 1 % is critical. For chemical modification there were some contributions in recent threads about nanotubes at Researchgate.
Only an idea, not tested yet. You may start with an organic water miscible solvent and solvent exchange with water as a second step. Maybe this works in combination with chemical modification.
You cannot disperse CNTs with such a heavy weight percentage in water directly. You can try the dispersion of CNTs by adding one nd half ml of 2 MET in water and then go for sonication for 2 hr. Hopefully then you can get the dispersion,
i my self for my thesis, dispers cnt in DMF and then use planetary mill about 1 hour to dispers carbon nao tube.i think yhis method is more useful than ultrasonic!
You can try surfactants "Investigation of Sodium Dodecyl Benzene Sulphonate Assisted Dispersion and Debundling of Single Wall Carbon Nanotubes." Priya Baskar Rao, Hugh J. Byrne, Journal of Physical Chemistry C, 12, 332-337 (2008), but in general be very careful of sonication "Ultrasound-Assisted SWNTs Dispersion: Effects of Sonication Parameters and Solvent Properties",
Qiaohuan Cheng, Sourabhi Debnath, Elizabeth Gregan and Hugh J. Byrne,
I have tried sonication once and it works. but you will loose the aspect ratio. It is possible to get stable suspention of nanotubes in water, however, you must takecare of the energy(power) and time of sonication. You will always get a better dispersion at the expense of some property.