The most abundant VOC will be acetone. Next, its inpurities and finally small amounts of monomers of your polymer along with their primary solvent and (if used) polymeris. activators.
I would not include acetone among most suitable solvents for poly(methyl methacrylate), i.e. PMMA ― for a few suitable solvents and for some particularly safe solvents you may check, respectively: