In order to calculate NMR pseudo-contact shift, one needs magnetic susceptibility tensor. Would it be valid to assume that the principal axes of such tensor always coincide with those of a g-tensor?
Effectively, in linear regime, the susceptibility tensor defined by [M ]= [X][H] can be diagonalized in the base of the principal axes of the single crystal, as indeed the tensor g. Its elements Xaa are also related to those of the tensor g.