Dear Federico, rhoenite is known in Tertiary alkali basalts of southern Slovakia since 1965, when it was first described as breakdown product of amphibole phenocrysts or as a groundmass mineral. More recently, it was also described in primary melt inclusions in peridotite and carbonatite xenoliths in the same basalt. The rhonite from melt inclusions is primary magmatic and crystallized from parental melt of basaltic trachyandesite to trachybasalt composition. Relevant electron microprobe data can be found here:
Huraiová M – Konečný P – Hurai V (2007) Nové nálezy minerálov skupiny enigmatitu na Slovensku. Mineralia Slovaca 39, 131-139 (posted on my research gate website)
and here:
Hurai V - Huraiova M - Konecny P - Thomas R (2007) Mineral-melt-fluid composition of carbonate-bearing cumulate xenoliths in Tertiary alkali basalts of southern Slovakia. Mienralogical Magazine 71, 63-79