In case of whole world we can calculate that how much CO2 are released (net released) based on the information of increased CO2 concentration. Using 5.137 x 10^18 kg as the mass of the atmosphere we know that 1 PPMV CO2=7.81 Gt CO2. Can we apply this information at local area level? If we can do this is it logical to use the ratio of the surface area of AOI (Area of Interest) to World Surface area (as we can't use the atmospheric weight of the world in case of a local area)?