For example, if copper doped single crystals have 6 hyperfine lines only, and each line is split up into four lines then we may say that two site occupation of Cu2+ ion.
This was one of the early predictions, and led Wolfgang Kratchmer to revisit the spectra of the soot he was generating by the arc discharge method.
http://pubs.rsc.org/en/content/articlelanding/1991/c3/c39910000412#!divAbstract
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