I have a siicon oxide film, which I am doping, and I'd like to know if there is any optical characterization technique that could be employed to detect the doping.
If it's only to get sure the presence of your dopant, UV-VIS spectroscopy may help you, you can get the band gap of your SiO before and after doping, additionally Raman spectroscopy could give you information about the disorder on the crystal lattice produced by the dopant.
If you doped anything in the host material then u will get a feasible change in optical properties of host material. Therefore, you can performed any optical characterization to observed this diversity.