When assessing the enrichment of an element in a sample compared to a background or reference level, it's essential to account for variations in the sample matrix. This is where the concept of a stable element comes into play.
Normalization is the process of dividing the concentration of an element in the sample by the concentration of a stable element in the same sample.
Characteristics of a Stable Element
A suitable stable element should exhibit the following characteristics:
Abundance: It should be present in sufficient quantities in the sample.
Stability: Resistant to anthropogenic influences and environmental changes
Conservative behavior: Its concentration should not be significantly affected by geochemical processes.
Representative of the lithogenic component: It should be a primary constituent of the sediment.
Commonly used stable elements in enrichment factor calculations include:
Aluminum (Al): Abundant, resistant to human activities, and a major constituent of clay minerals.
Iron (Fe): Widely distributed, relatively stable, and a significant component of many minerals.
Titanium (Ti): Highly resistant to weathering, often used in geochemical studies.
Zirconium (Zr): Another resistant element, commonly used in soil and sediment analysis.
Additional Considerations
The choice of stable element depends on the specific study and the elements being analyzed.
It's essential to justify the selection of the stable element based on its properties and relevance to the study area.
In some cases, multiple stable elements can be used to cross-validate results.