at nanofilm maybe can reach to confinement effect, so the energy gap will increase, in Al-Ni-Cr nanofilm the energy gap reached to 2.2 eV, this film suitable to fabricate solar cell (this research not published yet), also you can see: http://www.ajournal.co.uk/pdfs/BSvolume7(1)/BSVol.7%20(1)%20Article%201.pdf