One pot synthesis of both of these components is extremely difficult but you can try electrospum technique. Probably you will get cu nanostructure and TiO2 nanowires. 

Thanks for your reply.

But, Is it not possible through hydrothermal/ solvothermal technique??

I am extensively working on synthesis of such kind of materials via electrospum technique. I have no idea about hydrothermal or solvothermal process.

by chemical and electrochemical ways - any possibility exist.

Thanks for your question.... Thanks for this opportunity.... Why not  anchor Tio2 and Cu onto a support... It may be a possibility...

Thanks for your suggestion Mr. Suresh.

But Which type of Support??

We successfully anchored Zro2, Nio, Zno onto activated carbon. While anchoring NiO, we observed the presence of Ni on the carbon surface. For successful anchoring the carbon must have more graphitic content, which may help a lot during the carbothermal reduction process... Cu and Tio2 can be supported onto activated carbon...

Thermal conductivity and electric properties of epoxy composites filled with TiO2-coated copper nanowire. This paper may be helpful.

http://www.sciencedirect.com/science/article/pii/S0032386115302068