Yes, There are many possibility to change the structure of the alloy as we increase the percentage of alloy factor. There are so many research article which can show this. it depends on the phase diagram of the compositions. so you may read the phase diagram of your compositions for different area of that phase diagram.
When heated to temperature above Ac3, alloy steels have the same austenitic structure. During quenching austenite transforms into martensite or intermidiate structures depending on cooling rate. Alloying increases hardenability and some alloy elements like Al, Ti, V allow receiving fine microstructure. Main attention is paid to austenite - martensite transformation. Lysak and Vovk discovered that structure of martensite can be different depending on alloying.
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Please see: N.I.Kobasko, M.A.Aronov, J.A.Powell, G.E.Totten, Intensive Quenching Systems: Engineering and Design, ASTM International, 2010, 252 p, Chapter 1 which is in Nikolai Kobasko ResearchGate.
Of course it is. Just look at the handbook of binary phase diagrams.
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