I like to illustrate this question as below. In real solids, interactions of electrons and quasi- particles (phonon, spin (magnon), etc.,) are very important and that give rise to many important properties. For example, electron-phonon coupling gives superconducting property in some of the systems. Further, spin-phonon coupling gives rise to magnetic property in some of the magnetic materials. Similarly, the phonon-phonon coupling is responsible for anharmonicity which may give rise to the thermal expansion of the solids. Raman spectroscopy measurement gives the optical phonon energy of the systems. In addition, the width of the Raman peak is directly related to electron-phonon, phonon-phonon and spin-phonon coupling (interactions) exist in the system. Hence, the width of the Raman mode can measure (qualitatively) the interaction (electron-phonon, phonon-phonon and spin-phonon) of the system.
Whether, because of this interaction (electron-phonon, phonon-phonon, and spin-phonon coupling), the associated properties (superconductivity, thermal expansion, magnetic properties) are arising in material or vice versa?
In other words, is electron -phonon (phonon-phonon or spin-phonon) coupling cause or effect to give the associated property?
I kindly request you to answer this question and it will help my research work lot.
Thanks.