Usually the Cr(VI) is stable during oxidized condition. The generation of Cr(VI)/Cr(III) and their compounds is related to the pH/Eh of system. The Eh/pH diagram should be used for your system. You can use medusa software or MINTEQ for your purpose. Some preliminary information is presented at below:
1)Article Synthesis of nano-magnetic MnFe2O4 to remove Cr(III) and Cr(...
2) Article Application of enhanced electrokinetic approach to remediate...