Aromatic isocyanates are typically neutral to weakly basic, so using an acid-base indicator can help determine their acidity in solution. A suitable indicator for this purpose would be phenolphthalein.
Reasons for Choosing Phenolphthalein:
pH Range: It has a transition range of about 8.2 to 10, effectively detecting weak acidity or basicity.
Color Change: It changes from colorless in acidic solutions to pink in basic solutions, making it easy to observe any changes.
If you're working in a more acidic environment or need to detect lower pH values, consider using methyl orange (which transitions from red to yellow between pH 3.1 and 4.4) for more acidic conditions.
Summary:
Phenolphthalein: Best for weakly basic to neutral solutions.
Methyl Orange: Use for more acidic environments.
Conduct a preliminary test to confirm the indicator's effectiveness for your specific isocyanate solution.
High reactivity of aromatic isocyanates could sometimes pose difficult challenge. However, you can try any of the following indicators:
1. Bromothymol: This indicator changes the colour in the pH range between 6-7 which might be suitable for detecting acidity in aromatic isocyanates
2. Phenolphthalein is also a suitable indicator. Color changes would be observed in the pH range of 8.2- 9.8 which can be used to detect acidity or basicity in the medium