I suppose the times you are observed are the ones taken by the time dependant solver. Even if you specify a given time step the implicit method will take time steps in an adaptive fashion (time steps are taken looking at the error of the solution). You can tweak this in the time dependant solver but it requires a given level of understanding of what you are doing... Finally, and unless you retrieve the time steps taken by the solver, you should observe the solutions at the times you set in the time dependent step.
You can check the time-dependent solver---- time stepping-----steps taken by soler. Change it to Intermediate mode, it should fix your problem. Also you can check out the help documentation in comsol about this.