The simple answer is to determine the ratio of the Raman intensity peaks for amorphous phase vs. crystalline phase, assuming we have an accurate reference that could be used as a source. However, it is more completed, since Raman intensities for amorphous and crystalline phases also show wavelength dependent as can be seen in various publications such as: http://carbon.utsi.edu/downloads/raman_dlc_diamond.pdf
One may also look at the changes in the growth of the crystalline phase vs. amorphous phase as a function of growth conditions, such as:
The simple answer is to determine the ratio of the Raman intensity peaks for amorphous phase vs. crystalline phase, assuming we have an accurate reference that could be used as a source. However, it is more completed, since Raman intensities for amorphous and crystalline phases also show wavelength dependent as can be seen in various publications such as: http://carbon.utsi.edu/downloads/raman_dlc_diamond.pdf
One may also look at the changes in the growth of the crystalline phase vs. amorphous phase as a function of growth conditions, such as:
if you have a crystalline structure, you can observe phonon peaks which are typical for the substance. These small sharp peaks as in the last spectrum would refer to a crystalline structure. A broad or continues spectrum like the first spectrum indicates for an amorphous substance. I would recommend to study the literature concerning the phonon spectrum and analyse the different lines.