the pure Fe-salen spectra is in conformity with literature,but the composite is showing two extra peaks at 702 and 705 eV. Can anybody explain about why the peaks are coming.
I think that there is small charge shift because Fe 2p3/3 is 707 eV not 705 ... Have you analyze charge shift by looking C 1s ? And the second peak can be given by oxidation of Fe by Se. Oxide or Sulfide FeO or Fe2O3 or FeS can shift position ff the peek even 4 eV (FeS I do not know). So you have two peaks because one is Fe metallic and second is some selenid fo Fe. That is my idea ...
I am sorry, I thought that you mean selen Se, for which is more obvious. You mean Salen ligand. But answer is the same. It can cause oxidation of Fe and shift in binding energy to higher energy. And I agree with Konstantin I. Maslakov , the binding energies are too low and if hypothesis is correct even your peak 702 should be at 707. Without seeing spectras we cannot say more.