bcoz copper nanoparticles often get oxidised even at room temp.
See the following link and cross references:
http://dx.doi.org/10.4236/ojapps.2013.35043
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I am not getting pure copper nanoparticles, rather copper oxide is more formed.
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yield is very low in case of copper sulphate
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most of the plant have antioxidative property
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[Synthesizing Cu nanoparticles without using chemical reductants]
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