You can add 0.1 M HCl to the soil samples, after several hours, and measure the TOC of solutions. Additionally, you could also use the potassium dichromate volumetric method (the name is from a paper, in Section 2.1).
Thank you! I think, I will wait for solid combustion unit - we should obtain one soon. It is not really adventorous - but still should be more effective than other metods.