There have also been some cute measurements by K. Kern's group some years ago. I attended a talk of his at the time but guess that this must have been published in the meantime.
Observation of shell effects in superconducting nanoparticles of Sn (DOI: 10.1038/NMAT2768)
Experimental observation of thermal fluctuations in single superconducting Pb nanoparticles through tunneling measurements (DOI: 10.1103/PhysRevB.84.104525 & DOI: 10.1103/PhysRevB.84.219906)