You can use PLD and controlling the ablation time, distance, temperature you can vary the thickness of the film, you can have a look over this paper and in this website you will get some other publications,
I think ultrathin film formation can be perform by following techniques:
· Metal deposition techniques, such as vacuum evaporation and sputtering, have been well established and are cost effective. The dry process also eliminates the risk of contamination.
· Simple multi-layer deposition, for which each layer is passivated. This method is highly effective in suppressing the ripening effect
10 nm is the critical thickness for whatever deposition method you choose: deposition time does become so short that a consistent, repeatable deposition can hardly be guaranteed.
With very, very scrupulous control of all deposition parameters you might be able to achieve 5 nm uniform, repeatable thickness, But emphasis is on "might".