Hkl values are the labels of the crystallographic planes of a unit cell. To determine them, you must find what it is the unit cell of your polymer. Did you find it already or you need help with this?
You can try to learn how to this in some softwares, like EXPO, HighScore, etc. Or you could share your data, and then I could try to determine and teach you how to do it. But I can't promise I will make it, but I promise I will do the best I can.