In thin films grown by chemical technique from aqueous solutions some reactions expected may be masked and the stoichiometry obtained in the films may vary and how to determine the compositions.
Http://www.ndt.net/article/v09n06/ramachan/ramachan.htm
On the basis of all identified peaks which is possible only when the compound composition is in proper stoichiometrty
Using Vegards' law in ternary systems we can estimate stochiometry
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