I want to estimate the radius of gyration Rg of PEO polymer with Mw 4*10^6 a.m.u. and also the overlapping concentration c*, according to Rg=N^(3/5)*a, where a is the length of a monomer and N is the number of monomers of the polymer. The overlapping concentration c* is thus estimated as (Mw/NA)*Rg^(-3). The problem I met is how to determine the length of a monomer a?

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