As known, the spin exchange coupled Mn4+ leads to a narrowd singal, at ca. g=2.006 with the line width about 500 gauss. Why the birnessite MnO2 dispalys such wide spectrum? Is any other exchange interaction?
Yi Wan
Width of signal is due to the presence of the dipole-dipole and
exchange interaction between Mn4+ ions
Article Electron paramagnetic resonance of MnO2 powders
Yuri Mirgorod Dear Yuri, thank you very much for your answer. But what is the dipole-dipole interaction?
See for yourself on Wikipedia
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