Which parameters would you like to calculate? If you want to compute the diffusion coefficient D, you should carry out a family of cyclic voltammetry at different scan rates. Then you should analyze the peak current as a function of the square root of the scan rate.
Then, if the system is reversible, you can use the Randles Sevcik equation to calculate D.
For the case of the double-layer capacitance, an accurate calculation of this parameter can be obtained from electrochemical impedance spectroscopy rather than cyclic voltammetry.