Thanks again James Garry sir for your time and consideration and answer
I wanted to know at distance from planets and satellite.
What is the status of molecules/ atoms at High vacuum ,if electrons are spreading out side and expansion of molecules/atoms or separation of electrons at High vacuum
Atoms and molecules stay the same size. An atom of helium in an otherwise evacuated space does *not* 'expand' because of the reduced pressure. A ball bearing made of diamond does not expand in vacuum - and an electron is held to a nucleus by bonds stronger than those that hold two carbon atoms in a covalent bond.
The electron is bound very firmly to the nucleus and is utterly insensitive to the absence of 1 bar of pressure.
It's true, however, that at astronomically high pressures, atomic orbitals are deformed - and that is another topic. You need pressures commensurate with those in white dwarf stars before atoms become 'non-classical'.