There is a Index book for ICDD-JCPDS files. Almost all diffraction lab kipping this book those having a diffractometer. From that book you can find the exact file no or card no.
yes , you can use X`pert hi-score to find the JCPDS file number. Just click on Reference patterns and then go to retrieve by 'Restrictions'. select all your possible elements and load files. You will find all possible reference JCPDS files matching your sample.
Renuka's suggestion is OK but you should have the JCPDS -2 soft ware. It is an extra cost of the software. First you should confirm the availability of JCPDS-2 with your system or not?