It is known that temperary Hardness can be removed thermal treatment. It is due to the presence of Calcium, Megnesium, carbonate and bicarbonate ions. Same way Permanent hardness is due to the presence of Calcium, Megnesium, Sulphate and Chloride ions.
In principle if you have a permanent hardness it is permanent, and you can not remove. In any case to mitigate hardness the most common, and economical, treatment is steamming.
Permanent hardness is hardness (mineral content) that cannot be removed by boiling. When this is the case, it is usually caused by the presence of calcium sulfate and/or magnesium sulfates in the water, which do not precipitate out as the temperature increases. Ions causing permanent hardness of water can be removed using a water softener, or ion exchange column.
Total Permanent Hardness = Calcium Hardness + Magnesium Hardness
The calcium and magnesium hardness is the concentration of calcium and magnesium ions expressed as equivalent of calcium carbonate.
Total permanent water hardness expressed as equivalent of CaCO3 can be calculated with the following formula: Total Permanent Hardness (CaCO3) = 2.5(Ca2+) + 4.1(Mg2+)
Permanent hardness of water can be a removed by the following ways:
(a) By the use of soda:
Soda removes both temporary and permanent hardness. It is also inexpensive and easy to use. This makes it the ideal substance for softening water in the home.
(b) Other softening agents in the home:
It is difficult for the housewife to be very precise in the use of soda and the water softened by soda may often contain an excess of it, which even if it is slight, may damage certain fabrics. Hence, other softening agents could be used. They are:
(i) Soap:
Soap is used as a softening agent. However, the use of soap as a softening agent is extravagant on account of its high cost compared with soda.
(ii) Caustic soda:
t removes temporary hardness but reduces permanent hardness only when the lather is very slight.
(iii) Solution of Ammonia:
It may be used for softening water, when the fabrics to be treated would be harmed by soda. If used in excess, ammonia may destroy the Iustre of rayon's, discolour and injure animal fabrics and loosen the dyes of coloured articles. Since, it is not possible to be very certain of the quantity to be used; this is not practicable for softening water.
(iv) Borax:
It is useful for softening water containing over 20% of hardness. Borax is usually used to reduce the alkalinity of soap solution rather than to soften water.
(c) Removal of Permanent Hardness by the Base-Exchange Process:
Base exchange process' is a chemical method by which, softening of permanent hardness in water can be done on a large scale or for household purposes. It is the most popular and effective means of softening hard water. It was discovered by Dr. Robert Gans, who found out the natural minerals called 'Zeolites', which is very effective in softening water.
Rich antioxidants may remove the Mg and Ca in the form of MgO2, CaO2
For a somewhat related RG discussion, yet on brines, see: https://www.researchgate.net/post/Anyone-can-advise-me-on-how-can-we-reduce-the-High-concentration-of-Magnesium-Calcium-and-sodium-from-highly-saline-brine
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