there are numerous reports of this nature in the literature, one example being: http://journals.cambridge.org/article_S0007114589000267 or http://ajcn.nutrition.org/content/49/6/1146.short by Ceesay et al/westerterp et al back in the 80's.
there are also plenty moving forward in time, fast forward to 2005: Prediction of energy expenditure from heart rate monitoring during submaximal exercise, by Keytel et al (http://shapeamerica.tandfonline.com/doi/abs/10.1080/02640410470001730089), who successfully