Please see Fig 2 in xiaoguang mirror reaction file.
Fig 5 in Mulvihill file and Fig 4 in Rapid in situ file.
See snapshot from following dropbox share link
https://www.dropbox.com/s/0crilasfg4ee3jc/324324.pdf?dl=0
It is very interesting that in Fig 4 As III & As V are just separated, but the other two studies, As III & As V can not be separated completely. This is due to peaks width of As III & As V are generally broad. However in the article"rapid situ...", they employed Fe3O4@Ag nanoparticles, which is silver coating onto Fe3O4 particles, is it possible that this silver shell has influence on the vibrational width?
Looking forward your reply, great appreciated your help.