When we want to use a solvent or a mixture, we want to predict and evaluate different types of molecular interaction through some features of the chosen solvent.
Like, polar or apolar, protic or aprotic, etc..
Please help me with reference, book or link, etc …
I need to write a chapter in my thesis manuscript and use these concepts for discussion and interpretation of the studied liquid systems.
Thank you in advance.
I suggest you to refer the following books...
1. Handbook of solvents by George Wypych (Editor), ChemTec Publishing
2. Specific Intermolecular interactions of organic compounds by Alexei K.Baev, Springer
I suggest you to refer the following books...
1. Handbook of solvents by George Wypych (Editor), ChemTec Publishing
2. Specific Intermolecular interactions of organic compounds by Alexei K.Baev, Springer
Read about virial expansion and second virial coefficient, which is rather general framework to describe intermolecular interactions. Any book and many books :-)
You have to study and read a book and a small laboratory solvent solution of the floor.
there is no single parameter that represent exactly the effect of solvent therefore look for multi-parameter equation , that were used in literature to study solvent effects. .
you can read the book entitled (Advances in linear free energy relationships )ed. N.B.Chapman and J.Shorter, Plenum Press,London,1972.
Also read papers for R.W.Taft , M.J.Kamlet and J.L.Abboud 1978 - 1987.
Cf.: Ian. M. Smallwood, "Handbook of Organic Solvent Properties", Amold / Hodder Headline Group (London) and Halsted Press / John Wley & Sons Inc. (New York), 1996.
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