When i anneal my CZTS thin film coated over ITO substrate in H2S environmentat 550 C, the ITO reacts and its conductivity is lost. HOw we can protect ITO conductivity.
As previously stated ITO loses conductivity after 400 deg cel. You can try FTO which i've used upto 600 deg cel and quite stable. AZO is another alternative. Price is quite cheaper for AZO and FTO compared to ITO.
I experienced that FTO turns yellow (when used Ar+S) or black (when used H2S) in my annealing tube (470-550C) converting to sulfide (may be) and looses it's conductivity. Similar case for Mo. What would be a smart way to deal with it, scratching off??? I tried to do that, for FTO-colored material goes off, leaving no conductivity.