I am simulating a solar assisted absorption cooling in TRNSYS. I need to use double effect absorption chiller. For this purpose the required temperature is above 100C. How can I prevent it from boiling in hot water loop?
You can prevent boiling using a mixture of water and propylene glycol. In the following link you can find the variation of the boiling point of the mixture as a function of the percentage of glycol:
If you work with microchannels, and that their inner surface is clean and smooth (no nucleation sites) then you can have superheated water quite easily (up to 10`s of Kelvins above the saturation temperature). From an engineering point of view, it might not be safe though. Better use both answers hereabove.
(critical point, no difference between water and vapour)
Mit zunehmender Temperatur nähern sich die Eigenschaften von flüssigem und gasförmigem Wasser immer mehr aneinander an. Bei 374,12 °C ("kritische Temperatur") haben sich die Eigenschaften vollkommen aneinander angeglichen, so dass es keinerlei Unterschied mehr zwischen flüssigem und gasförmigem Wasser gibt. Folglich kann oberhalb dieser Temperatur weder ein Sieden noch ein Kondensieren stattfinden.
Aus den Dampfdruckdaten ist ersichtlich, wieviel Druck mindestens erforderlich ist, um Wasserdampf bei einer gegebenen Temperatur zu verflüssigen (zu kondensieren) oder umgekehrt, bei welcher Temperatur Wasser bei einem gegebenen Druck siedet.
As you can see: 5 bar is enough for 150°C, 16 bar is enough for 200°C.
Boiling Point of Propylene Glycol/Water Mixtures 60/100 can raise boiling point by 10 degree C, . This is what ocean water will do. PG is better than ocean water because
it is purposely design for that purpose. I don't believe it will has erosion problem.
But ocean water is definitely cheaper. For very high boiling point, one needs to increase pressure which can be quite expensive. (this answer was posted 6 hours ago, but for some reason, it did not show, so, I post it again.
As mentioned above using some additives to the water increases the boiling temperature. But what I suggest (as I have in my system) is using higher pressures for preventing water boiling. For example, at 5bar, the boiling temp is more than 150C.
When using TRNSYS, the easiest is to use diathermic oil instead of increasing pressure (no pressure in TRNSYS). You need to adjust the cp and implement the effect of higher viscosity on pumping power uptake.
Please bear in mind the difference between simulation and reality. In reality, an oil based system does not need high pressure components/seals/welding, which can add up to very high investment. But there are some drawbacks:
- High price per litre
- Higher viscosity at low temperatures and lower cp (compared to water)
- Safety regulations like fire prevention (which might revoke the monetary savings from low pressure installation)