I want to do DFT calculations of some metal complexes. But I don't know how to draw such a large molecule using Gaussview. Anyone please help me to solve the problem.
Drawing large molecules from scratch in usually not a good idea.
Best to use experimental xray structures of similar systems and for this best to use CCDC database. Searching through it requires a license (ask your university or crystaloography unit if they have one), but you can also find a paper where the structure was first solved and then request the .cif file for free at ccdc.cam.ac.uk/getstructures (gaussview reads .cif files or you can translate it to .mol2 / .xyz / .mol using openbabel).
Thank you very much for your kind response. In a metal complex containing Platinum what are the values of charge and multiplicity that should be used for optimization in Gaussian09