Do you mean that you want to fit the experimental data by the fitting function in the analysis program "Origin"?

In the analysis program "Origin", you can use "User-Defined Fitting Function."

Some instractions are available on the web written below.

http://www.originlab.com/doc/Origin-Help/UserDef-FitFunc 

You need to define your fitting function and perform fitting by the function.

I hope this information will solve your problem.

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