To prepare Ag nanoparticles i followed chemical reduction method. (http://dx.doi.org/10.1088/0957-4484/22/42/425601). I am in a mess. I would be very helpful if you please make my question answer.
So if the above reaction is correct, then your 25g of AgNO3 which contain 15.8g of Ag should lead to 34.3g of Ag-PVP nanoparticles. If you know or can measure the size of your nanoparticles then the volume concentration [mg/mL] can be converted to a number concentration [number of particles/mL].
You may want to read attached: "Nanoparticle counting: towards accurate determination of the molar concentration", Chemical Society Reviews 43(21) · August 2014
@Abdul Mass is conserved so you can't get 50 g of Ag from 25 g of AgNO3... Ulf has indicated the correct calculation above. You must remember that you're also stating that you'll bind the Ag nanoparticles (~ 16g) to PVP. As another point you can't get the nanoparticles in powder form - to preserve their < 100 nm status (the definition of nano) as free, discrete, independent articles, you'll need to keep them in colloidal suspension. See a recent discussion on RG: https://www.researchgate.net/post/How_to_deagglomerate_then_disperse_silica_nanoparticles_in_powder_form
A dry powder ('nanopowder' is an oxymoron as there are no free independent discrete particles of 20 nm in a powder even if the primary particles are 20 nm) is a fused collection of sub- and post-micron particles. They are aggregates not agglomerates. See:
Nov 11th, 2008. Dispersion and nanotechnology http://tinyurl.com/hpywsge
November 3rd, 2015 Adhesion and cohesion http://tinyurl.com/zwb2wlh
“If the particles are agglomerated and sub-micron it may be impossible to adequately disperse the particles……The energy barrier to redispersion is greater if the particles have been dried. Therefore the primary particles must remain dispersed in water….”
J H Adair, E. Suvaci, J Sindel, “Surface and Colloid Chemistry” Encyclopedia of materials: Science and Technology pp 8996 - 9006 Elsevier Science Ltd. 2001 ISBN 0-08-0431526