PTFE - poly-tetra-fluoro-ethylene -- (CF2)n - became a general name for co-polymers of CF2 - all of them are often called by using the general name "Teflon", but actually they are copolymers of (CF2). Two of such co-polymers are PFA and PFE - by using Key Words: PTFE, PFE and PFA - you can find all the formulas through the Google Search.
You are trying to choose the (CF2)-containing polymer in order to maximally reduce the adhesion to your Mould. But most of Researchers (including myself) try to choose the "Teflon"-co-polymer which will give the maximal adhesion - thus we are trying to solve the opposite problems. According to my experience PFA and PFE - show better adhesion to Polyimides and/or Metal - that is why i recommended you the to use homo-polymer (CF2) i.e., PTFE.
But since the results you obtained do not satisfy you - please try to use PFA and/or PFE suspensions which are also available as spray(s). It may happen that these sprays will do better for you than pure PTFE - but I doubt it.
Did you consider shrinking? May be you have, because processing conditions, a too small contraction or to high, depending of the geometrie of your part.
I have been working with such systems over 20 years.
And in my comment I actually discussed - which type of fluoro-polymer should be sprayed over the Kapton film - this is so obvious that just "flew out of my head"
Kapton film does work as a good anti-adhesive,
but the combination Kapton covered by one of Teflons - is superior.
(1) Negative Draw, which means that the Mold has some "under-cut" crevices, into which some small amount of the Polymer could flow and when solidified, removal is difficult - and may be not possible. The Answer to this Problem is to smoothen out the undercut and make sure that the Mold is without any negative draw;
(2) Many materials may need Full cooling to lower temperatures, before "stickiness" goes off. This problem is answered by Cooling the material to normal temperature;
(3) If the Mold is not smoothed out, even small "lines" could become undercut crevices that hold the product and removal may be difficult. Answer to this would need that the Mold is finished and polished. Perhaps one may resort to Hard-Chrome Plating after finishing to make easy removal of Product, apart from improving Finish and luster;
(4) In case all of these fail, one must use (after completing all of the above, in steps) Mold Release agents (usually Silicones) which are available as Sprays... There are many Manufacturers/suppliers... Here is one .. http://aerolgroup.com/products/productsafra-heavy-duty-silicone-sprays/ ... Also... one may Google and find out some one nearest to own location... Best regards